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- 產品名稱：Acrylic Primer#1602 LANG丙烯酸底漆
- 產品型號：
- 產品外觀：
- 產品概述
只用于動物實驗研究等
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| SAFETY DATA SHEET |
Issue Date | 26-Sept-2014 | Revision Date | 14-July-2015 | Version 3 |
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| 1. IDENTIFICATION |
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Product Identifier |
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Product Name | ACRYLIC PRIMER / JET SEAL |
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Other means of identification |
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SDS# | 041 |
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UN/ID No | UN1247 |
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Product Code | 1602, 1607, 1608 / 4102, 4106, 4107, 4108 |
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Recommended use of the chemical and restrictions on use |
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Recommended Use | Acrylic Primer - Acrylic bonding agent / Jet Seal - Acrylic sealing agent | |||
Acrylic Primer#1602 LANG丙烯酸底漆
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| 2. HAZARDS IDENTIFICATION | ||
Classification |
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Flammable liquids |
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| Category 2 |
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Skin Corrosion / Irritation |
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| Category 2 |
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Skin Sensitization |
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| Category 1 |
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Specific Target Organ Toxicity - Single Exposure |
| Category 3 |
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(Respiratory) |
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Signal word | Danger |
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Hazard statements | H225 | Highly flammable liquid and vapor. | |||
| H315 | Causes skin irritation. | |||
Acrylic Primer#1602 LANG丙烯酸底漆
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
Acrylic Primer / Jet Seal 041 v. 3 Page 1 of 8
Appearance Clear Physical state Liquid Odor Acrid
Precautionary Statements – Prevention
P210 Keep away from heat/sparks/open flames/ hot surfaces. No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary Statements – Response
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediay all contaminated clothing. Rinse skin with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P362 Take off contaminated clothing and wash before use.
P370+P378 In case of fire: Use CO2, for extinction.
Precautionary Statements – Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
Precautionary Statements – Disposal
P501 Dispose of contents/container in accordance with local regulation.
Hazardous Component(s) Contains methyl methacrylate
for labeling
Hazards not otherwise classified (HNOC) Not applicable
Other Information Harmful to aquatic life
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name | CAS No | Weight - % | Trade Secret |
Methyl Methacrylate | 80-62-6 | <100 | * |
*Specific chemical weight has been | withheld as a trade secret. |
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| 4. FIRST AID MEASURES |
First aid measures |
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Acrylic Primer / Jet Seal 041 v. 3 | Page 2 of 8 |
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Use personal protective equipment as required. Ensure adequate ventilation. Remove any contaminated clothing and wash thoroughly before reuse.
Inhalation | Remove victim to fresh air and keep at rest in a position comfortable for breathing. Keep patient warm and at |
| rest. Call a physician or poison control center immediay. |
Eye contact | Immediay flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing |
| for at least 15 minutes. Call a physician immediay. |
Ingestion | Do NOT induce vomiting. Drink plenty of water or milk immediay. Never give anything by mouth to an |
| unconscious person. Provide an estimate of the time at which the material was ingested and the amount of |
| the substance that was swallowed. Call a physician or poison control center immediay. |
Skin Contact | Wash off immediay with plenty of soap and water. Take off contaminated clothing. Wash contaminated |
| clothing before reuse. If skin irritation or rash occurs, get medical advice/attention. |
Most important symptoms and effects, both acute and delayed | |
Symptoms | May cause skin and eye irritation to the mucous membranes and upper respiratory tract. |
Indication of any immediate medical attention and special treatment needed | |
Note to physicians | Treat symptoms conventionally, after thorough decontamination. |
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| 5. FIRE-FIGHTING MEASURES |
Extinguishing Media
Suitable: Chemical foam, carbon dioxide (CO2), dry chemical
Unsuitable: Water spray
Specific hazards arising from the chemical
For bulk size >1L – High temperatures, inhibitor depletion, accidental impurities, or exposure to radiation or oxidizers may cause spontaneous polymerizing reaction generating heat/pressure. Closed containers may rupture or explode during a runaway polymerization. Use a water spray or fog to reduce or direct vapors. Extremely flammable. Vapors are heavier than air and may spread along the floors. Vapors may travel to source of ignition and flash back. Heat/impurities may cause pressure to build and/or rupture closed containers, spreading fire, increasing risk or burns/injuries.
Hazardous Combustion Products: Carbon oxides
Sensitivity to Mechanical Impact: No
Sensitivity to Static Discharge: Yes
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Fight fire from a safe location.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Environmental precautions Prevent product from entering drains. Spillages or uncontrolled discharges into watercourses must
be alerted to the appropriate regulatory body.
Methods and material for containment and clean-up
Method for containment Absorb with earth, sand or other non-combustible material and transfer to containers for later
disposal. DO NOT use combustible materials such as sawdust.
Method for clean-up Use only non-sparking tools. Wash all affected areas with plenty of warm water and soap.
Acrylic Primer / Jet Seal 041 v. 3 Page 3 of 8
If anticipated that prolonged and repeated skin contact will occur during use of this product, wear gloves for routine industrial use. If necessary, refer to US OSHA 29CFR SS1910.138 or the appropriate standards of Canada or the EC member states. Wear suitable protective clothing.
Depending on the use of this product, safety glasses or goggles may be worn. If necessary, refer to US OSHA 29CFR SS1910.133, Canadian standards or the European Standard EN 166. Ensure that an eyewash station, sink or washbasin is available in case of exposure to eyes.
Keep in original container.
Strong oxidizing agents, strong reducing agents, free-radical generators, inert gases, oxygen scavengers
Material has strong solvent properties and can soften paint and rubber.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Consideration should be given to the work procedures involved and the potential extent of exposure as they may determine whether a higher level of protection is required. The following information is given as general guidance.
Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks, flame and other sources of ignition (i.e. pilot lights, electric motors and static electricity). Protect from direct sunlight. Keep container closed to prevent water absorption and contamination. Methacrylate stored in bulk must be kept in contact with air (oxygen). Keep at a temperature not exceeding 25°C.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Observe precautions found on the label. Keep containers closed when not in use. All equipment used when handling the product must be grounded. Use non-sparking hand tools and explosion-proof electrical equipment. Avoid contact with skin and eyes. Avoid breathing vapors or mists. Use only in well-ventilated areas. Vapors are heavier than air and may travel along the floor and in the bottom of containers. Take precautionary measures against static discharges. Wash thoroughly after handling. Use personal protection recommended in Section 8. Contaminated work clothing should not be allowed out of the workplace. Keep away from heat, sparks, open flames, and hot surfaces. NO SMOKING.
Conditions for safe storage, including any incompatibilities
Storage Conditions
Packaging materials
Incompatible materials
Exposure guidelines
Chemical Name | ACGIH TLV | OSHA PEL | NIOSH IDLH |
Methyl Methacrylate | S 100 ppm | TWA:100 ppm | IDLH: 1,000 ppm |
80-62-6 | TWA: 50 ppm | TWA: 410 mg/m3 | TWA: 100 ppm |
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| TWA: 410 mg/m3 |
Appropriate engineering controls
Engineering controls Apply technical measures to comply with the occupational exposure limits. Eyewash stations
Individual protection measures, such as personal protective equipment
Eye / face protection
Skin and body protection
Acrylic Primer / Jet Seal 041 v. 3 Page 4 of 8
Respiratory protection | Wear suitable respiratory equipment if exposure to levels above the occupational exposure limit is | |||
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| likely. A suitable mask with filter type A may be appropriate. In the event of formation of particularly | ||
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| high levels of vapor, a self-contained breathing apparatus may be appropriate. | ||
General hygiene considerations | Handle in accordance with good industrial hygiene and safety practice. | |||
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| 9. PHYSICAL AND CHEMICAL PROPERTIES |
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Information on basic physical and chemical properties |
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Physical state |
| Liquid | Odor | Acrid |
Appearance |
| Liquid | Odor threshold | Not determined |
Color |
| Clear |
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Property |
| Values | Remarks / Method |
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pH |
| Not determined |
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Melting point / | freezing point | Not determined |
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Boiling point / boiling range | 101°C / 214° F |
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Flash point |
| 11.5°C / 52.7°F |
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Evaporation rate | 3.1 | Butyl acetate = 1 |
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Flammability (solid, gas) | n/a (liquid) |
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Flammability limits in air |
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Upper flammability limit | 12.5% |
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Lower flammability limit | 2.12% |
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Vapor pressure |
| 28mm Hg | @ 20°C |
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Vapor density |
| 3.5 | @15.5°C (Air = 1) |
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Specific gravity |
| 0.891 | Water = 1 |
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Water solubility |
| 1.6 wt% |
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Solubility in other solvents | Not determined |
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Partition coefficient | Not determined |
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Autoignition temperature | 421°C / 790°F |
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Decomposition temperature | Not determined |
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Kinematic viscosity | Not determined |
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Dynamic viscosity | Not determined |
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Explosive properties | Not determined |
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Oxidizing properties | Not determined |
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Other information |
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Density |
| 0.891 g/mL |
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| 10. STABILITY AND REACTIVITY |
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Reactivity | Not reactive under normal conditions |
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Chemical stability Unstable / reactive upon depletion of inhibitor
Possibility of hazardous reactions
None under normal processing
Hazardous polymerization Hazardous polymerization may occur. Monomer vapors are inhibited and may form polymers in vent or flame arresters, resulting in blockage of vents.
Conditions to avoid
Temperatures above 25°C (77°F), localized heat sources (e.g. drum or band heaters), oxidizing conditions, freezing conditions, direct sunlight, ultraviolet radiation, inert gas blanketing
Incompatible materials
Strong oxidizing agents, strong reducing agents, free-radical generators, inert gases, oxygen scavengers
Material has strong solvent properties and can soften paint and rubber.
Hazardous decomposition products Carbon oxides
Acrylic Primer / Jet Seal 041 v. 3 Page 5 of 8
May cause allergic skin reaction.
Not classifiable as a human carcinogen
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| 11. TOXICOLOGICAL INFORMATION |
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Information on likely routes of exposures |
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Product information |
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Inhalation | Avoid breathing vapors or mists. |
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Eye contact | Causes severe eye irritation. |
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Skin contact | Causes skin irritation. |
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Ingestion | Not expected to be toxic following ingestion of amount recommended for use. |
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Component information |
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Chemical Name |
| ORAL LD50 | DERMAL LD50 |
| INHALATION LC50 |
Methyl Methacrylate |
| 7872 mg/kg (rat) | >5 g/kg (rabbit) |
| 400 ppm (rat) 1 h |
80-62-6 |
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| 4632 ppm (rat) 4 h |
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Information on physical, chemical and toxicological effects |
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Symptoms | May cause skin and eye irritation. May cause irritation to the mucous membranes and upper respiratory tract. | ||||
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Carcinogenicity
Chemical Name | ACGIH | IARC | NTP | OSHA |
Methyl Methacrylate | - | Group 3 | - | - |
80-62-6 |
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IARC (International Agency | for Research on Cancer) | Group 3 IARC components are “not classifiable as human carcinogens” | ||
STOT – single exposure May cause respiratory irritation. May cause drowsiness or dizziness.
Numerical measures of toxicity – Product Not determined
The following values are calculated based on chapter 3.1 of the GHS document.
ATEmix (oral) | 7874 | mg/kg |
ATEmix (dermal) | 5005 | mg/kg |
ATEmix (inhalation-gas) | 400 | mg/kg |
12. ECOLOGICAL INFORMATION
Ecotoxicity Harmful to aquatic life.
Chemical Name | Algae / aquatic plants | Fish | Toxicity to | Crustacea |
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Methyl | 170: 96 h | 125.5-190.7: 96 h Pimephales | - | 69: 48 h Daphnia magna |
Methacrylate | Psuedokirchneriella | promelas mg/L LC50 static; |
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80-62-6 | subcapitata mg/L EC50 | 153.9-341.8: 96 h Lepomis macrochirus mg/L |
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| LC50 static; |
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| 170-206: 96 h Lepomis macrochirus mg/L |
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| LC50 flow -through; |
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| 243-275: 96 h Pimephales promelas mg/L |
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| LC50 flow-through; |
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| 326.4-426.9 96 h Poecilia reticulata mg/L |
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| LC50 static; |
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| >79: 96 h Oncorhynchus mykiss mg/L LC50 |
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| flow-through; |
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| >79: 96 h Oncorhynchus mykiss mg/L LC50 |
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| static |
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Acrylic Primer / Jet Seal 041 v. 3 |
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| Persistence and degradability Not readily biodegradable |
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| Bioaccumulation | Not determined |
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| Mobility | Potential for mobility in soil is very high. |
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| Chemical Name |
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| Methyl Methacrylate |
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| 0.7 |
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| Other adverse effects | COD = 88% (28 days), DOC removal > 95% (28 days) |
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| 13. DISPOSAL CONSIDERATIONS |
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| Waste treatment methods |
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| Disposal of wastes |
| Follow all local and national government regulations in disposing material or contaminated | |||||||||||
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| For U.S. - Dispose of in accordance with federal, state and local regulations. When discarded, it is | |||||||||
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| considered a hazardous waste by the EPA under RCRA. The reportable quantity for methyl | |||||||||
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| methacrylate is 1000 lb. (40 CFR Part 302). Add excess inhibitor before disposing. | |||||||||
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| Contaminated Packaging |
| Reuse of empty drums or containers is not recommended. Employees should be advised of the | |||||||||||
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| potential hazards due to residual material associated with empty containers. Dispose of all empty | |||||||||
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| containers properly in accordance with federal, state and local regulations. | |||||||||
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| Chemical Name |
| RCRA |
| RCRA – Basis for Listing | RCRA – D Series Wastes |
| RCRA – U Series Wastes | ||||||
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| Methyl Methacrylate |
| U162 |
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| Included in waste stream; | - |
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| U162 | |||
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| 80-62-6 |
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| F039 |
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| Methyl Methacrylate |
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| Toxic Ignitable |
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| 80-62-6 |
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| 14. TRANSPORTATION INFORMATION |
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| UN / ID No |
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| UN1247 |
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| Proper shipping name |
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| Methyl Methacrylate monomer, stabilized |
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| Hazard Class |
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| 3 |
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| Packing Group |
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| II |
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| Reportable Quantity (RQ) |
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| 1000 lb. |
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| IATA |
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| UN / ID No |
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| UN1247 |
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| Proper shipping name |
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| Methyl Methacrylate monomer, stabilized |
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| 3 |
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| II |
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| UN / ID No |
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| UN1247 |
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| Proper shipping name |
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| Methyl Methacrylate monomer, stabilized |
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| Hazard Class |
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| 3 |
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| II |
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Acrylic Primer / Jet Seal 041 v. 3 Page 7 of 8
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| 15. REGULATORY INFORMATION |
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International Inventories |
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TSCA | Listed |
| United States Toxic Substances Control Act, Section 8(b) Inventory |
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DSL | Listed |
| Canadian Domestic Substances List |
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EINECS | Listed |
| European Inventory of Existing Chemical Substances |
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EU Regulations | EC No. 1272/2008 (CLP) Classification, Labeling, Packaging |
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| Medical Devices Directive 93/42/EEC - Class I Medical Devices |
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US Federal Regulations |
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Chemical Name |
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| Weight % |
| SARA 313 Threshold Values % |
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Methyl Methacrylate |
| 80-62-6 |
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| < 100 |
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| 1.0 |
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SARA 311 / 312 Hazard Categories |
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Chemical Name |
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| CWA – Reportable |
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| CWA – Toxic |
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| CWA – Priority |
| CWA – Hazardous |
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| Quantities |
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| Pollutants |
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| Pollutants |
| Substances |
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Methyl Methacrylate |
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| 1,000 lb. |
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80-62-6 |
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Chemical Name |
| Hazardous Substances |
| CERCLA / |
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| SARA RQ |
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| Final |
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Methyl Methacrylate |
| 1,000 lb. |
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| 1,000 lb. / 454 kg |
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80-62-6 |
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US State Right-to-Know Regulations |
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Chemical Name |
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| New Jersey |
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Methyl Methacrylate | 80-62-6 |
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16. OTHER INFORMATION
NFPA | Health Hazards |
| Flammability | Instability |
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| 2 |
| 3 | 2 |
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HMIS | Health Hazards |
| Flammability | Physical Hazards |
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| 2 |
| 3 | 2 |
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Issue Date | 26-Sept-2014 |
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Revision Date | 14-July-2015 |
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Revision Note | Section 2 – revise classification categories, revise some Hazard Statements and Precautionary Statements,, | ||||
| add hazardous component for labeling info |
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Information to be updated in due course | Hazard pictograms listed in this SDS to be added to product label | ||||
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release. It is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.